S
- (Rovenkivskyi Raion) Stepove
- (Dovzhanskyy Rayon) Shakhtarske
- (Dovzhanskyy Rayon) Shyroke
- (Dovzhanskyy Rayon) Svitlychne
- (Svativskyi Raion) Svitlenke
- (Shchastynskyi Raion) Stepove
- (Luhanskyi Raion) Stukalova Balka
- (Luhanskyi Raion) Simeikyne
- Semeykino
- (Alchevskyi Raion) Sentianivka
- (Alchevskyi Raion) Slov`yanoserbsk
- (Shchastynskyi Raion) Shchastia
- Schast'ye
- (Shchastynskyi Raion) Stanytsia Luhanska
- Svatove
- Starobil's'k
- Sverdlovs'k
- Stakhanov
- Syeverodonets'k