S
- (Starobilskyi Raion) Svitle
- (Starobilskyi Raion) Shapran
- (Starobilskyi Raion) Sukhoye
- (Starobilskyi Raion) Stepove
- (Dovzhanskyy Rayon) Sklyarov
- (Starobilskyi Raion) Solone
- (Rovenkivskyi Raion) Shlyakhtin
- (Dovzhanskyy Rayon) Shlyakhtino
- (Dovzhanskyy Rayon) Sredniy
- (Rovenkivskyi Raion) Shirokiy
- (Alchevskyi Raion) Stepanovka
- (Luhanskyi Raion) Shymshynivka
- (Svativskyi Raion) Serhiivka
- (Sievierodonetskyi Raion) Serdyukovka
- (Sievierodonetskyi Raion) Skelya
- (Alchevskyi Raion) Slavyanoserbsk
- (Dovzhanskyy Rayon) Skubriy
- (Alchevskyi Raion) Sadovyy
- (Sievierodonetskyi Raion) Serbinovka
- (Shchastynskyi Raion) Serednoteple
- (Sievierodonetskyi Raion) Synetskyi
- (Svativskyi Raion) Shatkivka
- (Starobilskyi Raion) Sychanske
- (Starobilskyi Raion) Stepove
- (Alchevskyi Raion) Stepove
- (Rovenkivskyi Raion) Shyrokyi
- (Rovenkivskyi Raion) Soniachne
- (Rovenkivskyi Raion) Stepove
- (Rovenkivskyi Raion) Sadovyi
- (Svativskyi Raion) Sosnovyi