S
- (Rovenkivskyi Raion) Shchotove
- (Svativskyi Raion) Sharivka
- (Dovzhanskyy Rayon) Sharapkino
- (Svativskyi Raion) Shapovalovka
- (Svativskyi Raion) Shaparivka
- (Sievierodonetskyi Raion) Shakhta Tomasha
- (Svativskyi Raion) Shakhove
- (Dovzhanskyy Rayon) Sievero-Hundorivskyi
- (Dovzhanskyy Rayon) Sievernyi
- (Shchastynskyi Raion) Sergeyevskiy
- (Starobilskyi Raion) Senkove
- (Starobilskyi Raion) Semykozivka
- (Alchevskyi Raion) Seleznivske
- (Luhanskyi Raion) Samsonivka
- (Rovenkivskyi Raion) Sadovo-Khrustalnenskyi
- (Starobilskyi Raion) Sadky
- (Luhanskyi Raion) Sabivka
- (Starobilskyi Raion) Sosnivka
- (Svativskyi Raion) Storozhivka
- (Shchastynskyi Raion) Sotenne
- (Alchevskyi Raion) Stare
- (Svativskyi Raion) Sirotino
- (Svativskyi Raion) Sofiivka
- (Svativskyi Raion) Sudbynka
- (Starobilskyi Raion) Solonivka
- (Starobilskyi Raion) Shelestivka
- (Sievierodonetskyi Raion) Surovtsivka
- (Svativskyi Raion) Solntsevo
- (Svativskyi Raion) Samsonovka
- (Rovenkivskyi Raion) Svistunova