S
- (Sievierodonetskyi Raion) Shchedryshcheve
- (Starobilskyi Raion) Sychivka
- (Svativskyi Raion) Svystunivka
- (Starobilskyi Raion) Svitle
- (Sievierodonetskyi Raion) Svetlichnoye
- (Alchevskyi Raion) Sutagan
- (Svativskyi Raion) Sukhoy Baglay
- (Starobilskyi Raion) Sukhoy
- (Dovzhanskyy Rayon) Sukhodilsk
- (Sievierodonetskyi Raion) Sukhodol
- (Luhanskyi Raion) Sukhodol
- (Alchevskyi Raion) Sukhodil
- (Starobilskyi Raion) Sukhanivka
- (Starobilskyi Raion) Striltsivka
- (Shchastynskyi Raion) Stepnyi Yar
- (Starobilskyi Raion) Stepne
- (Luhanskyi Raion) Stepnoye
- (Alchevskyi Raion) Stepanivka
- (Svativskyi Raion) Stelmakhivka
- (Svativskyi Raion) Statyvchyne
- (Shchastynskyi Raion) Staryi Aidar
- (Starobilskyi Raion) Starobel’skiy
- (Sievierodonetskyi Raion) Stara Krasnianka
- (Sievierodonetskyi Raion) Srednyaya Teplaya
- (Shchastynskyi Raion) Spivakivka
- (Starobilskyi Raion) Spasovskiy
- (Rovenkivskyi Raion) Spartak
- (Svativskyi Raion) Solontsi
- (Svativskyi Raion) Solidarne
- (Sievierodonetskyi Raion) Sokilnyky