B
- (Starobilskyi Raion) Butove
- (Svativskyi Raion) Beokhnekrugloye
- (Alchevskyi Raion) Berezivske
- (Shchastynskyi Raion) Blahovishchenka
- (Starobilskyi Raion) Bilolutsk
- (Luhanskyi Raion) Bilorichenskyi
- (Dovzhanskyy Rayon) Biloskeliuvate
- (Svativskyi Raion) Belosvitovka
- (Dovzhanskyy Rayon) Berehove
- (Dovzhanskyy Rayon) Bratske
- (Svativskyi Raion) Berezovatka
- (Starobilskyi Raion) Berezovka
- (Dovzhanskyy Rayon) Berezivka
- (Starobilskyi Raion) Berezove
- (Starobilskyi Raion) Besedovka
- (Shchastynskyi Raion) Bezhynove
- (Dovzhanskyy Rayon) Birjukowo
- (Rovenkivskyi Raion) Blahivka
- (Rovenkivskyi Raion) Bobrykove
- (Sievierodonetskyi Raion) Bobrove
- (Svativskyi Raion) Bahachka
- (Luhanskyi Raion) Buran
- (Alchevskyi Raion) Bairachky
- (Sievierodonetskyi Raion) Bilohorivka
- Belogorovka
- Biryukove
- (Alchevskyi Raion) Bile
- Beloye
- (Svativskyi Raion) Bilokurakyne
- (Starobilskyi Raion) Bilovods'k