S
- (Fastiv Raion) Stepove
- (Fastiv Raion) Sofiivka
- (Bilotserkivska Miskrada) Savran
- (Bilotserkivska Miskrada) Skrebyshi
- (Obukhiv Raion) Stepok
- (Obukhiv Raion) Shcherbanivka
- (Bilotserkivska Miskrada) Stepanivka
- (Bilotserkivska Miskrada) Sofiika
- (Bilotserkivska Miskrada) Sukhyi Yar
- (Borispol’skiy Rayon) Sosnivka
- (Obukhiv Raion) Saliv
- (Obukhiv Raion) Shevchenkivka
- (Borispol’skiy Rayon) Stovpiahi
- (Borispol’skiy Rayon) Somkova Dolyna
- (Borispol’skiy Rayon) Strokova
- (Borispol’skiy Rayon) Shevchenkove
- (Obukhiv Raion) Stari Bezradychi
- (Bilotserkivska Miskrada) Savyntsi
- (Borispol’skiy Rayon) Sotnykivka
- (Vyshgorodskiy Rayon) Sychivka
- (Brovary Raion) Svitylnia
- (Vyshgorodskiy Rayon) Svarom’ya
- (Vyshgorodskiy Rayon) Suvyd
- (Obukhiv Raion) Sushchany
- (Vyshgorodskiy Rayon) Sukholuchchia
- (Bilotserkivska Miskrada) Sukholisy
- (Vyshgorodskiy Rayon) Sukachi
- (Borispol’skiy Rayon) Studenyky
- (Bilotserkivska Miskrada) Stryzhavka
- (Obukhiv Raion) Stritivka